Non-measurable events are ones to which the probability function in the situation assigns no probability. Philosophically speaking, non-measurable events come in two varieties:
Non-measurable events that should not have any probability assignment.
Non-measurable events that should have a probability assignment.
Type (1) non-measurable events are the kinds of weird events that can be constructed from the Hausdorff and Banach-Tarski paradoxes, as well as perhaps (this is less clear) the Vitali non-measurable sets.
But I think there are also type (2) non-measurable events relative to standard choices of probability functions. For instance, suppose that in each universe of an infinite multiverse a fair coin is tossed countably infinitely often.
How likely is it that in at least one universe all the coin tosses are heads? If the universes form a countable infinity, classical probability theory gives an answer: zero. But if the universes form an uncountable infinity, classical probability theory gives no answer at all—the standard completed product measure makes the event be non-measurable. However, intuitively, there should be an answer in at least some cases. If the number of universes is much larger than the number of possible countable sequences of coin tosses (i.e., is much larger than 2ω), we would expect the probability to be 1 or close to it. We can coherently extend the standard probability function to give that answer. But we can also coherently extend it to give a different answer, including the answer that the probability of an all-heads universe is zero, even if the number of universes is a gigantic infinite cardinality.
We don’t want to just make up an answer here. We want the answer to be derivable in some way resembling the proof of the theorem that if you toss a coin infinitely many times, you’ve got probability 1 of getting heads at least once.
I suppose we could take it to be a metaphysical axiom that if you have K disjoint collections each with M coin tosses, then if K and M are infinite and K > M, then with probability one at least one collection yields all heads. But it would be nice to have more than just intuition here, and in similar problems.