On the question of what has a substantial form, I have tended to think something similar to van Inwagen’s answer to the question of what wholes there are. Namely, I assign form to:
organisms, and
fundamental objects in physics that are good candidates for being substances.
Regarding 2, if the correct physics is particle-based (which I doubt, in light of the apparent possibility of the world being in a superposition of states with different numbers of particles), these will be particles, or at least those particles that aren’t part of an organism. If the correct physics is field-based, the substances in physics will be fields (or maybe just one field-like object, namely “the global wavefunction”).
A lot of Aristotelians have substances, with forms, that are intermediate between (1) and (2), such as hydrogen atoms or water molecules or chunks of iron, and maybe astronomical objects like stars or galaxies. While I don’t have a knock-down argument against such substances, I also don’t see any reason to posit them.
My reasons for positing form for organisms and fundamental physical objects are quite different. For organisms, the reasons are largely normative. Parrots and oak trees can flourish or languish; they have ends and proper functions. In the case of humans, the normativity extends much further. Furthermore, we need well-defined boundaries for organisms for ethical reasons—there is reason not to harm an organism, especially but not only a human one—and there need to be well-defined persistence conditions for humans for moral responsibility. Something needs to ground all this. And the best candidate is form.
It is a central commitment of Aristotelianism that all of physical reality is grounded in physical substances and their accidents. But it is false that all of physical reality is grounded in organisms. There was a time when the physical universe had no organisms. So we need other substances. The fundamental objects of physics are the best candidates. They are active and have very clear kind-boundaries. The electromagnetic field is a different kind of thing from the gravitational field (which is just spacetime, according to Einstein). Photons are clearly different from electrons. (Though if it turns out that particle number is indeterminate, then particles won’t be the fundamental objects of physics.)
Granted, it is not obvious (and somewhat counterintuitive) that organisms have well-defined kind-boundaries and identity conditions. And it is not obvious (and somewhat counterintuitive) that fundamental physical objects have norms. But here I just take these to be consequences of the theory. Organisms have well-defined kind-boundaries and identity conditions, but we don’t know where they lie. Fundamental physical objects have normative properties, but I suspect they are perfect instances of their kind, and always do exactly what they should (C. S. Lewis says something like that in Mere Christianity).
Neither of my two reasons applies much to objects like atoms, molecules, chunks of stuff, or astronomical objects. There is no strong independent reason to suppose that they have normative properties in their own right, and their boundaries are, if not quite as fuzzy as those of organisms, pretty fuzzy. How far apart do I get to move a hydrogen atom from two oxygen atoms before I destroy a water molecule? How many sodium and chloride ions do I add to water to change it from water with impurities to a salt solution? (I suppose the concept of impurity pulls in the direction of thinking there are normative properties. But here is a reason to think this is mistaken. If impure water is languishing, then we have reason to distill water independently of any practical benefit to any organism, just for the sake of the water itself. That seems absurd.)
That the reasons don’t apply doesn’t show that there aren’t other reasons to posit substantial forms for these other candidates. But I don’t see such reasons. And so we can apply Ockham’s razor.